Notes
Includes index , Machine generated contents note: 1. Fundamental Principles and Functions -- 1.1 First Law of Thermodynamics -- 1.1.1 Heat, Work and Internal Energy -- 1.1.2 Enthalpy and Heat Capacity -- 1.1.3 Enthalpy Change (AH) -- 1.2 Second Law of Thermodynamics -- 1.2.1 Reversible and Irreversible Processes -- 1.2.2 Entropy(S) -- 1.2.3 Criterion of Equilibrium -- 1.2.4 Heat Engines -- 1.3 Auxiliary Functions -- 1.3.1 Free Energies -- 1.3.2 Effect of Pressure on Free Energy -- 1.3.3 Effect of Temperature on Free Energy -- 1.3.4 Some Useful Equations -- 1.4 Third Law of Thermodynamics -- 1.4.1 Third Law of Thermodynamics -- 1.4.2 Absolute Entropies. -- 1.5 Calculation of Enthalpies and Free Energies -- 1.5.1 Standard States -- 1.5.2 Heat of Formation -- 1.5.3 Heat of Reaction -- 1.5.4 Adiabatic Flame Temperature -- 1.5.5 Gibbs Free Energy Changes -- 2. Solutions -- 2.1 Behaviour of Gases -- 2.1.1 Ideal Gases -- 2.1.2 Fugacities and Real Gases -- 2.2 Thermodynamic Functions of Mixing -- 2.2.1 Activities and Chemical Potentials -- 2.2.2 Partial Properties -- 2.3 Behaviour of Solutions -- 2.3.1 Ideal Solutions -- 2.3.2 Non-ideal Solutions and Excess Properties -- 2.3.3 Dilute Solutions -- 2.3.4 Gibbs-Duhem Equation -- 2.3.5 Solution Models -- 3. Equilibria -- 3.1 Reaction Equilibria -- 3.1.1 Equilibrium Constant -- 3.1.2 Criteria of Reaction Equilibrium -- 3.1.3 Effect of Temperature on Equilibrium Constant -- 3.1.4 Effect of Pressure on Equilibrium Constant -- 3.1.5 Le Chatelierʹs Principle -- 3.1.6 Alternative Standard States -- 3.1.7 Interaction Coefficients -- 3.1.8 Ellingham Diagram -- 3.2 Phase Equilibria -- 3.2.1 Phase Rule -- 3.2.2 Phase Transformations -- 3.2.3 Phase Equilibria and Free Energies -- 4. Phase Diagrams -- 4.1 Unary Systems -- 4.1.1 Pressure-Temperature Diagrams -- 4.1.2 Allotropy -- 4.2 Binary Systems -- 4.2.1 Binary Liquid Systems -- 4.2.2 Binary Systems without Solid Solution -- 4.2.3 Binary Systems with Solid Solution -- 4.2.4 Thermodynamic Models -- 4.3 Ternary Systems -- 4.3.1 Composition Triangles -- 4.3.2 Polythermal Projections -- 4.3.3 Isothermal Sections -- 5. Electrochemistry -- 5.1 Electrochemical Concepts and Thermodynamics -- 5.1.1 Basic Electrochemical Concepts -- 5.1.2 Electrochemical Cell Thermodynamics -- 5.2 Electrochemical Cells -- 5.2.1 Cells and Electrodes -- 5.2.2 Concentration Cells -- 5.3 Aqueous Solutions -- 5.3.1 Activities in Aqueous Solutions -- 5.3.2 Solubility Products -- Appendices -- I Heats of formation, standard entropies and heat capacities -- II Standard free energies of formation -- III Properties of Selected Elements -- IV Standard half-cell potentials in aqueous solutions -- Index.
